TY - JOUR
T1 - Solvent motion controls the rate of intramolecular electron transfer in solution
AU - Kosower, Edward M.
AU - Huppert, Dan
PY - 1983/4/15
Y1 - 1983/4/15
N2 - The fluorescence decay times (τ-F) for conversion (by intramolecular electron transfer) of the S1,np state into the S1,ct state of 6-(4-methylphenyl) amino-2-naphthalenesulfon-N,N-dimethylamide (TNSDMA) correlate well with the constant-charge dielectric relaxation times [τ1v = (ε00/εs) τ1] in linear alcohols. Solvent motion thus controls certain intramolecular electron transfers.
AB - The fluorescence decay times (τ-F) for conversion (by intramolecular electron transfer) of the S1,np state into the S1,ct state of 6-(4-methylphenyl) amino-2-naphthalenesulfon-N,N-dimethylamide (TNSDMA) correlate well with the constant-charge dielectric relaxation times [τ1v = (ε00/εs) τ1] in linear alcohols. Solvent motion thus controls certain intramolecular electron transfers.
UR - http://www.scopus.com/inward/record.url?scp=11744374652&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(83)80726-X
DO - 10.1016/0009-2614(83)80726-X
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:11744374652
SN - 0009-2614
VL - 96
SP - 433
EP - 435
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 4
ER -