TY - JOUR
T1 - Solvent-free synthesis of open-framework metal sulfate oxalates with dia and ths topologies
AU - Guo, Caihong
AU - Chen, Cheng
AU - Wang, Kangcai
AU - Zeng, Hongmei
AU - Lin, Zhien
N1 - Publisher Copyright:
© 2017
PY - 2017/11
Y1 - 2017/11
N2 - Two open-framework metal sulfate oxalates, namely, H2dmen·Mn(SO4)(ox) (1) and H4bapp·[In2(SO4)3(ox)2(H2O)2]·H2O (2), were prepared under solvent-free conditions, where dmen = N,N-dimethylethylenediamine, ox = oxalate, and bapp = N,N′-bis(3-aminopropyl)piperazine. Structural analyses reveal that compound 1 has a dia-type net with 12-ring channels, while compound 2 has a ths-type net with 20-ring channels. The proton-conducting properties of compound 2 were also investigated.
AB - Two open-framework metal sulfate oxalates, namely, H2dmen·Mn(SO4)(ox) (1) and H4bapp·[In2(SO4)3(ox)2(H2O)2]·H2O (2), were prepared under solvent-free conditions, where dmen = N,N-dimethylethylenediamine, ox = oxalate, and bapp = N,N′-bis(3-aminopropyl)piperazine. Structural analyses reveal that compound 1 has a dia-type net with 12-ring channels, while compound 2 has a ths-type net with 20-ring channels. The proton-conducting properties of compound 2 were also investigated.
KW - Inorganic-organic hybrid solids
KW - Proton conduction
KW - Solvent-free synthesis
KW - Sulfate
KW - Topology
UR - http://www.scopus.com/inward/record.url?scp=85024898985&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2017.07.007
DO - 10.1016/j.inoche.2017.07.007
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AN - SCOPUS:85024898985
SN - 1387-7003
VL - 85
SP - 96
EP - 99
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
ER -