TY - JOUR
T1 - Solvent-free synthesis of new metal phosphate-oxalates with helical-chain and slablike structures
AU - Wang, Wei
AU - Luan, Lindong
AU - Yang, Meng
AU - Wang, Kangcai
AU - Lin, Zhien
N1 - Publisher Copyright:
© 2016
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Two metal phosphate-oxalate, namely, H3pmdeta ⋅ Ga2(HPO4)(H2PO4)(C2O4)3 (1) and H2mpip ⋅ Mn2(H2PO4)2(C2O4)2 ⋅ H2O (2), were prepared under solvent-free conditions, where pmdeta = N',N″,N″-pentamethyldiethylenetriamine and mpip = 1-methylpiperzaine. Compound 1 features a helical-chain structure containing cyclic inorganic building block. Compound 2 has a slablike structure with a kgd net. The magnetic and proton-conducting properties of compound 2 were also investigated.
AB - Two metal phosphate-oxalate, namely, H3pmdeta ⋅ Ga2(HPO4)(H2PO4)(C2O4)3 (1) and H2mpip ⋅ Mn2(H2PO4)2(C2O4)2 ⋅ H2O (2), were prepared under solvent-free conditions, where pmdeta = N',N″,N″-pentamethyldiethylenetriamine and mpip = 1-methylpiperzaine. Compound 1 features a helical-chain structure containing cyclic inorganic building block. Compound 2 has a slablike structure with a kgd net. The magnetic and proton-conducting properties of compound 2 were also investigated.
KW - Inorganic-organic hybrid solids
KW - Oxalate
KW - Phosphate
KW - Proton conductivity
KW - Solvent-free synthesis
UR - http://www.scopus.com/inward/record.url?scp=85007000289&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2016.12.002
DO - 10.1016/j.inoche.2016.12.002
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AN - SCOPUS:85007000289
SN - 1387-7003
VL - 75
SP - 46
EP - 48
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
ER -