Soluble ferrocene conjugates for incorporation into self-assembled monolayers

C. J. Yu, Yoochul Chong, Jon Faiz Kayyem, Michael Gozin

Research output: Contribution to journalArticlepeer-review

Abstract

A series of phenylethynyl oligomers (I-V) possessing a ferrocene and thiol at each termini have been synthesized. These oligomers have been designed to overcome the inherent insolubility of this class of complexes by substitution at the phenyl groups with methyl and propoxy substituents. Several new reactions for preparing arenethiol-protected compounds are described. Interestingly, the generation of an arenethiol anion during base- or fluoride-catalyzed deprotection has been characterized.

Original languageEnglish
Pages (from-to)2070-2079
Number of pages10
JournalJournal of Organic Chemistry
Volume64
Issue number6
DOIs
StatePublished - 19 Mar 1999
Externally publishedYes

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