Salalen: A hybrid Salan/Salen tetradentate [ONNO]-type ligand and its coordination behavior with group IV metals

Adi Yeori; Shimrit Gendler; Stanislav Groysman; Israel Goldberg; Moshe Kol

doi:10.1016/j.inoche.2003.11.023

Salalen: A hybrid Salan/Salen tetradentate [ONNO]-type ligand and its coordination behavior with group IV metals

Adi Yeori, Shimrit Gendler, Stanislav Groysman, Israel Goldberg, Moshe Kol^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A straightforward synthesis of Salalens, tetradentate [ONNO]-type ligands comprised of an amine-phenolate and an imine-phenolate subunits is introduced. The Salalen ligand precursor reacted with titanium(IV) ethoxide and with tetrakis(dimethylamido)zirconium to yield the corresponding [(Salalen)MX ₂]-type C₁-symmetric complexes in a single isomeric form, indicating that Salalen is a genuine hybrid of its parent Salan and Salen ligands.

Original language	English
Pages (from-to)	280-282
Number of pages	3
Journal	Inorganic Chemistry Communication
Volume	7
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2003.11.023
State	Published - Feb 2004

Keywords

Salalen
Salan
Salen
Titanium
Zirconium

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10.1016/j.inoche.2003.11.023

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title = "Salalen: A hybrid Salan/Salen tetradentate [ONNO]-type ligand and its coordination behavior with group IV metals",

abstract = "A straightforward synthesis of Salalens, tetradentate [ONNO]-type ligands comprised of an amine-phenolate and an imine-phenolate subunits is introduced. The Salalen ligand precursor reacted with titanium(IV) ethoxide and with tetrakis(dimethylamido)zirconium to yield the corresponding [(Salalen)MX 2]-type C1-symmetric complexes in a single isomeric form, indicating that Salalen is a genuine hybrid of its parent Salan and Salen ligands.",

keywords = "Salalen, Salan, Salen, Titanium, Zirconium",

author = "Adi Yeori and Shimrit Gendler and Stanislav Groysman and Israel Goldberg and Moshe Kol",

note = "Funding Information: We thank the Israel Ministry of Science, Culture and Sports, and the Israel Science Foundation for financial support. We thank Ms. Dvora Reshef for technical assistance. ",

year = "2004",

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doi = "10.1016/j.inoche.2003.11.023",

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T2 - A hybrid Salan/Salen tetradentate [ONNO]-type ligand and its coordination behavior with group IV metals

AU - Yeori, Adi

AU - Gendler, Shimrit

AU - Groysman, Stanislav

AU - Goldberg, Israel

AU - Kol, Moshe

N1 - Funding Information: We thank the Israel Ministry of Science, Culture and Sports, and the Israel Science Foundation for financial support. We thank Ms. Dvora Reshef for technical assistance.

PY - 2004/2

Y1 - 2004/2

N2 - A straightforward synthesis of Salalens, tetradentate [ONNO]-type ligands comprised of an amine-phenolate and an imine-phenolate subunits is introduced. The Salalen ligand precursor reacted with titanium(IV) ethoxide and with tetrakis(dimethylamido)zirconium to yield the corresponding [(Salalen)MX 2]-type C1-symmetric complexes in a single isomeric form, indicating that Salalen is a genuine hybrid of its parent Salan and Salen ligands.

AB - A straightforward synthesis of Salalens, tetradentate [ONNO]-type ligands comprised of an amine-phenolate and an imine-phenolate subunits is introduced. The Salalen ligand precursor reacted with titanium(IV) ethoxide and with tetrakis(dimethylamido)zirconium to yield the corresponding [(Salalen)MX 2]-type C1-symmetric complexes in a single isomeric form, indicating that Salalen is a genuine hybrid of its parent Salan and Salen ligands.

KW - Salalen

KW - Salan

KW - Salen

KW - Titanium

KW - Zirconium

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JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

IS - 2

ER -

Salalen: A hybrid Salan/Salen tetradentate [ONNO]-type ligand and its coordination behavior with group IV metals

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