TY - JOUR
T1 - Rotational effects on intramolecular radiationless transitions in a large molecule
AU - Amirav, Aviv
AU - Jortner, Joshua
AU - Terazima, M.
AU - Lim, B. C.
N1 - Funding Information:
This researchw ass upportedin partb y theU nited StatesA rmy throughi ts EuropeanR esearchO ffice (to JJ), by the Fund for BasicR esearcho f theI srael Academyo f Sciences(t o AA) andb y a Grant (CHE 8418442f)r omt heN ationalS cienceF oundation( to ECL).
PY - 1987/1/9
Y1 - 1987/1/9
N2 - We report the observation of a pronounced rotational-state dependence for the fluorescence quantum yield and fluorescence decay from the S1(0,0+1160 cm-1) state of jet-cooled 9-cyanoanthracene. We attribute these results to the effects of Coriolis rotational-vibrational interaction on intramolecular vibrational energy redistribution, which influence electronic relaxation.
AB - We report the observation of a pronounced rotational-state dependence for the fluorescence quantum yield and fluorescence decay from the S1(0,0+1160 cm-1) state of jet-cooled 9-cyanoanthracene. We attribute these results to the effects of Coriolis rotational-vibrational interaction on intramolecular vibrational energy redistribution, which influence electronic relaxation.
UR - https://www.scopus.com/pages/publications/4243526094
U2 - 10.1016/0009-2614(87)87046-X
DO - 10.1016/0009-2614(87)87046-X
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AN - SCOPUS:4243526094
SN - 0009-2614
VL - 133
SP - 179
EP - 184
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 2
ER -