TY - JOUR
T1 - Real-time monitoring of organic reactions with two-dimensional ultrafast TOCSY NMR spectroscopy
AU - Herrera, Antonio
AU - Fernández-Valle, Encarnación
AU - Martínez-Álvarez, Roberto
AU - Molero, Dolores
AU - Pardo, Zulay D.
AU - Sáez, Elena
AU - Gal, Maayan
PY - 2009/8/10
Y1 - 2009/8/10
N2 - A quick look reveals all: A two-dimensional ultrafast TOCSY experiment in one scan is presented and used to study the synthesis of pyrimidine from an aliphatic ketone, a nitrile, and Tf 2O. 525 two-dimensional TOCSY experiments were recorded, and the reactants, intermediates, and products could be monitored (see picture; blue=product; gray, green, and pink=intermediates).
AB - A quick look reveals all: A two-dimensional ultrafast TOCSY experiment in one scan is presented and used to study the synthesis of pyrimidine from an aliphatic ketone, a nitrile, and Tf 2O. 525 two-dimensional TOCSY experiments were recorded, and the reactants, intermediates, and products could be monitored (see picture; blue=product; gray, green, and pink=intermediates).
KW - Heterocycles
KW - NMR spectroscopy
KW - Reaction mechanisms
KW - TOCSY
UR - http://www.scopus.com/inward/record.url?scp=70349903241&partnerID=8YFLogxK
U2 - 10.1002/anie.200902387
DO - 10.1002/anie.200902387
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AN - SCOPUS:70349903241
SN - 1433-7851
VL - 48
SP - 6274
EP - 6277
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 34
ER -