Quantum effects on electron-transfer processes

Mordechai Bixon*, Joshua Jortner

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

69 Scopus citations

Abstract

The non-adiabatic multiphonon theory of electron transfer provides a complete description of nuclear tunnelling and final-state excitation phenomena, which modify the classical Marcus theory. Ultrafast electron-transfer processes, where the electronic process competes with medium-induced vibrational relaxation, cannot be handled by the conventional theory, being amenable to description in terms of quantum-mechanical models.

Original languageEnglish
Pages (from-to)17-29
Number of pages13
JournalFaraday Discussions of the Chemical Society
Volume74
DOIs
StatePublished - 1982

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