Polymer-based LFP cathode/current collector microfiber-meshes with bi- and interlayered architectures for Li-ion battery

Edi Mados, Inbar Atar, Yuval Gratz, Mai Israeli, Olga Kondrova, Victor Fourman, Dov Sherman, Diana Golodnitsky*, Amit Sitt*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations


In this study, we report the development of a free-standing fiber-based mesh cathode made of electrospun composite microfibers containing 80 wt% lithium iron phosphate (LFP), as well as conductive microfibers containing carbon nano-fillers acting as the current collector (CC). Neither the electrode nor the current collector undergoes post-fabrication treatment or calcination. Scanning electron microscopy confirmed that the meshes are constructed of well-shaped microfibers and exhibit a high porosity, enabling efficient electrolyte penetration and improved electron and ion-transport channels. Two cathode architectures of the LFP/polymer-based CC meshes were explored: bilayered and interlayered. Both architectures are characterized by a high surface-to-volume ratio. The interlayered structure showed superior electrochemical performance due to enhanced LFP-CC fiber-to-fiber contacts and reduced resistance. Comparative analysis with electrospun LFP on aluminum foil revealed comparable specific capacity but higher polarization in the electrospun LFP/CC meshes, attributed to increased internal resistance and limited fiber-to-fiber contacts. However, the electrospun interlayered LFP/CC mesh exhibited significantly higher gravimetric energy density (197 Wh/kg (LFP + CC) and 94 Wh/kg (LFP + Al), respectively), offering lightweight and higher-energy-density electrode materials, thus guiding the design of high-performance flexible lithium-ion batteries.

Original languageEnglish
Article number234397
JournalJournal of Power Sources
StatePublished - 30 May 2024


FundersFunder number
Tel Aviv University
Israel Science Foundation1682/22


    • Electrospinning
    • Flexible electrode
    • Interlayered architecture
    • LFP
    • Mesh-electrode


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