@article{03628b0bd7c94b4fb41db431ae1e6433,
title = "Photoactivation of ruthenium phosphite complexes for olefin metathesis",
abstract = "The commercially available catalyst cis-Caz-1 is extremely robust, especially when reactions are performed in an atmosphere of air. This phosphite-containing ruthenium complex only shows olefin metathesis activity at high temperatures. Herein, we report photoactivation of cis-Caz-1 at room temperature with UVA light. Thus, a wide variety of olefin metathesis reactions was performed under mild conditions with good yields. In addition, we report the synthesis, characterization, and catalytic activity of a phosphite-chelated ruthenium benzylidene complex, cis-PhosRu-1, which can be efficiently activated either by irradiation with visible light (λ = 405 nm) or by heat.",
keywords = "latent catalysis, olefin metathesis, phosphates, photochemistry, ruthenium",
author = "Or Eivgi and Stefano Guidone and Alexander Frenklah and Sebastian Kozuch and Israel Goldberg and Lemcoff, {N. Gabriel}",
note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = jul,
day = "6",
doi = "10.1021/acscatal.8b01637",
language = "אנגלית",
volume = "8",
pages = "6413--6418",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "7",
}