Phosphorus mediated imidazolinium to oxazolium ring rearrangement

Deependra Bawari, Solomon Volodarsky, Yael Ginzburg, Kuldeep Jaiswal, Pooja Joshi, Roman Dobrovetsky*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

An unexpected rearrangement occurred when an imidazolinium based OCO pincer-type ligand (1) reacted with PCl3 producing a chlorophosphine with a pendant oxazolium "arm"(3). The mechanism of this rearrangement was studied both experimentally and by density functional theory (DFT) computations. The deprotonation of 3 led to further unexpected results.

Original languageEnglish
Pages (from-to)16478-16482
Number of pages5
JournalDalton Transactions
Volume50
Issue number45
DOIs
StatePublished - 7 Dec 2021

Funding

FundersFunder number
Ministry of Science, Technology and Space65692
Israel Science Foundation237/18

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