Perturbations around steady states in a continuous stirred tank reactor

K. Bar-Eli*, W. Geiseler

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Perturbations around steady states of a system of cerium or manganese bromide and bromate ions in a sulfuric acid solution, in a continuous stirred tank reactor (CSTR), are investigated. Two kinds of perturbations are discussed, namely, small-species and large-constraint ones. The feasibility of measuring a particular rate constant by following the system behavior after a small perturbation is analyzed. Some general theorems regarding this behavior are obtained. Large perturbations, namely, those that cause a transition of the system from one steady state to another, are analyzed and an approximate relationship between the perturbations' intensity and length is developed. The results are in good agreement with the experimental data.

Original languageEnglish
Pages (from-to)1352-1357
Number of pages6
JournalJournal of Physical Chemistry
Volume87
Issue number8
DOIs
StatePublished - 1983

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