Oscillations in the bromate-bromide-cerous system. The simplest chemical oscillator

K. Bar-Eli, W. Geiseler

Research output: Contribution to journalArticlepeer-review

Abstract

The instability of the cerium-bromate-bromide system in an open-flow (CSTR) system was investigated near the critical point. Near this critical point Hopf s bifurcation occurs, causing stable states to become unstable. Domains of single or three unstable steady states occur, with possible oscillations around them. A good agreement is obtained between the calculated and experimental oscillation domains on the various subspaces of constraints. This oscillator is the simplest chemical oscillator fully understood in terms of elementary reactions.

Original languageEnglish
Pages (from-to)3769-3774
Number of pages6
JournalJournal of Physical Chemistry
Volume87
Issue number19
DOIs
StatePublished - 1983

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