Optical resolution of amine N-oxide by diastereoisomeric complex formation with optically active host compound

Fumio Toda; Koji Mori; Zafra Stein; Israel Goldberg

doi:10.1016/S0040-4039(00)99594-7

Optical resolution of amine N-oxide by diastereoisomeric complex formation with optically active host compound

Fumio Toda^*, Koji Mori, Zafra Stein, Israel Goldberg

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Optical stereoisomers of various amine N-oxides with one or two chiral centers can effectively be resolved by selective crystalline complexation with an optically active host. Intermolecular interaction schemes and absolute configurations of the N-oxide guests are revealed by crystallographic analyses of the diastereoisomeric complexes.

Original language	English
Pages (from-to)	1841-1844
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	14
DOIs	https://doi.org/10.1016/S0040-4039(00)99594-7
State	Published - 1989

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title = "Optical resolution of amine N-oxide by diastereoisomeric complex formation with optically active host compound",

abstract = "Optical stereoisomers of various amine N-oxides with one or two chiral centers can effectively be resolved by selective crystalline complexation with an optically active host. Intermolecular interaction schemes and absolute configurations of the N-oxide guests are revealed by crystallographic analyses of the diastereoisomeric complexes.",

author = "Fumio Toda and Koji Mori and Zafra Stein and Israel Goldberg",

year = "1989",

doi = "10.1016/S0040-4039(00)99594-7",

language = "אנגלית",

volume = "30",

pages = "1841--1844",

journal = "Tetrahedron Letters",

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T1 - Optical resolution of amine N-oxide by diastereoisomeric complex formation with optically active host compound

AU - Toda, Fumio

AU - Mori, Koji

AU - Stein, Zafra

AU - Goldberg, Israel

PY - 1989

Y1 - 1989

N2 - Optical stereoisomers of various amine N-oxides with one or two chiral centers can effectively be resolved by selective crystalline complexation with an optically active host. Intermolecular interaction schemes and absolute configurations of the N-oxide guests are revealed by crystallographic analyses of the diastereoisomeric complexes.

AB - Optical stereoisomers of various amine N-oxides with one or two chiral centers can effectively be resolved by selective crystalline complexation with an optically active host. Intermolecular interaction schemes and absolute configurations of the N-oxide guests are revealed by crystallographic analyses of the diastereoisomeric complexes.

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U2 - 10.1016/S0040-4039(00)99594-7

DO - 10.1016/S0040-4039(00)99594-7

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AN - SCOPUS:0011789762

SN - 0040-4039

VL - 30

SP - 1841

EP - 1844

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 14

ER -

Optical resolution of amine N-oxide by diastereoisomeric complex formation with optically active host compound

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