TY - JOUR
T1 - On the reaction of the NH2 radical with ozone
AU - Bulatov, V. P.
AU - Buloyan, A. A.
AU - Cheskis, S. G.
AU - Kozliner, M. Z.
AU - Sarkisov, O. M.
AU - Trostin, A. I.
PY - 1980
Y1 - 1980
N2 - The reaction NH2 + O3 was studied by flash photolysis of NH3 + O3 (λ > 250 nm) using intracavity laser spectroscopy. This reaction governs NH2 decay at low ozone pressures (PO3 < 0.5 Torr) and its rate constant is k1 = (1.2 ± 0.3) × 10−13 cm3/s At PO3 > 0.5 Torr,NH2 decay is due to the following mechanism: NH2 + O3 → NH2O+O2 (1), NH2O+ O3 → NH2 + 2O2 (8),NH2O → NHOH (10) with k8 = (2.0 ± 1.5) × 10−14 cm3/s.k10 = (1.3 = 0.1) × 103 s−1.
AB - The reaction NH2 + O3 was studied by flash photolysis of NH3 + O3 (λ > 250 nm) using intracavity laser spectroscopy. This reaction governs NH2 decay at low ozone pressures (PO3 < 0.5 Torr) and its rate constant is k1 = (1.2 ± 0.3) × 10−13 cm3/s At PO3 > 0.5 Torr,NH2 decay is due to the following mechanism: NH2 + O3 → NH2O+O2 (1), NH2O+ O3 → NH2 + 2O2 (8),NH2O → NHOH (10) with k8 = (2.0 ± 1.5) × 10−14 cm3/s.k10 = (1.3 = 0.1) × 103 s−1.
UR - http://www.scopus.com/inward/record.url?scp=84977617581&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(80)85160-8
DO - 10.1016/0009-2614(80)85160-8
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AN - SCOPUS:84977617581
SN - 0009-2614
VL - 74
SP - 288
EP - 292
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 2
ER -