@article{bfb63cc9eba54f538a06932928882b19,
title = "Observation of resonant two-photon photodetachment of water cluster anions via femtosecond photoelectron spectroscopy",
abstract = "Photoexcitation of the (H2O)-n (n=20-100) clusters with 100 fs pulses at 800 nm results in an increasing propensity for two-photon electron photoejection with increasing cluster size. This increase correlates with the size range (n≈30) where the first excited electronic state drops below the electron continuum, and the electronic absorption band approaches the energy of the 800 nm pump photon. No above-threshold, two-photon detachment is observed for n=20. Differences in the shape of the resonant two-photon photoelectron spectrum compared to that arising from direct (high energy) photodetachment are interpreted in terms of the vibrational state selection created in the resonant step.",
author = "Weber, \{J. M.\} and J. Kim and Woronowicz, \{E. A.\} and Weddle, \{G. H.\} and I. Becker and O. Cheshnovsky and Johnson, \{M. A.\}",
note = "Funding Information: We are grateful to Department of Energy for support of this work, as well as the National Science Foundation, which provided funds for the ultrafast laser system under the University Research Instrumentation program. This research was partly supported by the US–Israel Binational Science Foundation. We also thank Prof. K.D. Jordan for valuable discussions pertaining to the interpretation of this data. ",
year = "2001",
month = may,
day = "18",
doi = "10.1016/S0009-2614(01)00295-0",
language = "אנגלית",
volume = "339",
pages = "337--342",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier B.V.",
number = "5-6",
}