Novel boracycles from 2-amino-2-methylpropan-1-ol and borane methyl sulfide: Synthesis and X-ray crystal structures

Ofir Baum, Israel Goldberg, Morris Srebnik

Research output: Contribution to journalArticlepeer-review

Abstract

On reacting the simple 1,2-amino alcohol: 2-amino-2-methylpropan-1-ol, with borane methyl sulfide (BMS), the expected five member oxazaborolidine ring is not obtained. Instead, two polycyclic structures with trigonal boron atoms 6 and 7 were obtained, and their structure were determined by X-ray crystallography. Compound 6 was obtained in 39% yield and compound 7 was obtained in 7% yield.

Original languageEnglish
Pages (from-to)1993-1997
Number of pages5
JournalJournal of Organometallic Chemistry
Volume691
Issue number9
DOIs
StatePublished - 15 Apr 2006

Keywords

  • Boranes methyl sulfide
  • Crystal structure
  • Oxazaborolidine

Fingerprint

Dive into the research topics of 'Novel boracycles from 2-amino-2-methylpropan-1-ol and borane methyl sulfide: Synthesis and X-ray crystal structures'. Together they form a unique fingerprint.

Cite this