Nonmonotonic temperature dependence of the rates of ion-molecule reactions

Eran Rabani, D. M. Charutz, R. D. Levine

Research output: Contribution to journalArticlepeer-review

Abstract

A minimum in the temperature dependence of the reaction rate of fast reactions can be due to a double minimum potential along the reaction coordinate. The two important points are the steric effects of the central barrier along the reaction coordinate and the extensive recrossing of this barrier. General considerations and detailed classical trajectory computations are presented.

Original languageEnglish
Pages (from-to)10551-10553
Number of pages3
JournalJournal of Physical Chemistry
Volume95
Issue number26
DOIs
StatePublished - 1991

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