TY - JOUR
T1 - NMR Spectroscopy of Bilirubin and its Derivatives
AU - Kaplan, Doron
AU - Navon, Gil
PY - 1983
Y1 - 1983
N2 - Literature NMR data of bilirubin and related compounds and their interpretation in terms of structure, solution conformation and dynamic properties have been reviewed. 1H‐spectrum assignments as well as solvent and temperature dependencies of the chemical shifts are described. Proton exchange rates, longitudinal relaxation times and nuclear Overhauser enhancements are surveyed. NMR is shown to provide knowledge on the basic structure, conformation, tautomerism, hydrogen bonding, acidity constants, segmental motion of side‐chains, interconversion between enantiomers and aggregation—disaggregation of these compounds in solution.
AB - Literature NMR data of bilirubin and related compounds and their interpretation in terms of structure, solution conformation and dynamic properties have been reviewed. 1H‐spectrum assignments as well as solvent and temperature dependencies of the chemical shifts are described. Proton exchange rates, longitudinal relaxation times and nuclear Overhauser enhancements are surveyed. NMR is shown to provide knowledge on the basic structure, conformation, tautomerism, hydrogen bonding, acidity constants, segmental motion of side‐chains, interconversion between enantiomers and aggregation—disaggregation of these compounds in solution.
UR - http://www.scopus.com/inward/record.url?scp=84985059613&partnerID=8YFLogxK
U2 - 10.1002/ijch.198300026
DO - 10.1002/ijch.198300026
M3 - מאמר
AN - SCOPUS:84985059613
VL - 23
SP - 177
EP - 186
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
SN - 0021-2148
IS - 2
ER -