New open-framework beryllium phosphates with hcb, sql, and bnn topologies

Kangcai Wang; Na Yang; Dingguo Xu; Daibing Luo; Zhien Lin

doi:10.1016/j.inoche.2015.06.020

New open-framework beryllium phosphates with hcb, sql, and bnn topologies

Kangcai Wang, Na Yang, Dingguo Xu^*, Daibing Luo, Zhien Lin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Three new beryllium phosphates, namely, H₃aep·Be₂(PO₄)₂(H₂PO₄)·H₂O (1), H₂tmdp·Be₃(HPO₄)₃(PO₄CH₃)·2.25H₂O (2), and H₂dmpda·Be₃(PO₄)(HPO₄)₂(H₂PO₄) (3), were prepared under solvothermal conditions. These compounds display different open-framework structures with hcb (for 1), sql (for 2), and bnn (for 3) topologies, respectively. The formation of phosphate ester from in situ esterification reaction of phosphoric acid and methanol is noteworthy.

Original language	English
Pages (from-to)	95-98
Number of pages	4
Journal	Inorganic Chemistry Communication
Volume	58
DOIs	https://doi.org/10.1016/j.inoche.2015.06.020
State	Published - 22 Jun 2015
Externally published	Yes

Keywords

Beryllium
Gas adsorption
Phosphates
Solvothermal synthesis
Topology

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10.1016/j.inoche.2015.06.020

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title = "New open-framework beryllium phosphates with hcb, sql, and bnn topologies",

abstract = "Three new beryllium phosphates, namely, H3aep·Be2(PO4)2(H2PO4)·H2O (1), H2tmdp·Be3(HPO4)3(PO4CH3)·2.25H2O (2), and H2dmpda·Be3(PO4)(HPO4)2(H2PO4) (3), were prepared under solvothermal conditions. These compounds display different open-framework structures with hcb (for 1), sql (for 2), and bnn (for 3) topologies, respectively. The formation of phosphate ester from in situ esterification reaction of phosphoric acid and methanol is noteworthy.",

keywords = "Beryllium, Gas adsorption, Phosphates, Solvothermal synthesis, Topology",

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T1 - New open-framework beryllium phosphates with hcb, sql, and bnn topologies

AU - Wang, Kangcai

AU - Yang, Na

AU - Xu, Dingguo

AU - Luo, Daibing

AU - Lin, Zhien

PY - 2015/6/22

Y1 - 2015/6/22

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AB - Three new beryllium phosphates, namely, H3aep·Be2(PO4)2(H2PO4)·H2O (1), H2tmdp·Be3(HPO4)3(PO4CH3)·2.25H2O (2), and H2dmpda·Be3(PO4)(HPO4)2(H2PO4) (3), were prepared under solvothermal conditions. These compounds display different open-framework structures with hcb (for 1), sql (for 2), and bnn (for 3) topologies, respectively. The formation of phosphate ester from in situ esterification reaction of phosphoric acid and methanol is noteworthy.

KW - Beryllium

KW - Gas adsorption

KW - Phosphates

KW - Solvothermal synthesis

KW - Topology

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JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

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New open-framework beryllium phosphates with hcb, sql, and bnn topologies

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Keywords

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