New open-framework beryllium phosphates with hcb, sql, and bnn topologies

Kangcai Wang, Na Yang, Dingguo Xu*, Daibing Luo, Zhien Lin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review


Three new beryllium phosphates, namely, H3aep·Be2(PO4)2(H2PO4)·H2O (1), H2tmdp·Be3(HPO4)3(PO4CH3)·2.25H2O (2), and H2dmpda·Be3(PO4)(HPO4)2(H2PO4) (3), were prepared under solvothermal conditions. These compounds display different open-framework structures with hcb (for 1), sql (for 2), and bnn (for 3) topologies, respectively. The formation of phosphate ester from in situ esterification reaction of phosphoric acid and methanol is noteworthy.

Original languageEnglish
Pages (from-to)95-98
Number of pages4
JournalInorganic Chemistry Communication
StatePublished - 22 Jun 2015
Externally publishedYes


  • Beryllium
  • Gas adsorption
  • Phosphates
  • Solvothermal synthesis
  • Topology


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