New macromolecular host systems. Preparation and structure of certain functionalized 2,6-diaryl-cis-1,3,5,7-tetraoxadecalin podand compounds and macro-m-cyclophanes

Sarah Abramson, Eli Ashkenazi, Israel Goldberg, Moshe Greenwald, Harald Jatzke, Michaela Vardi, Sarah Weinman, Benzion Fuchs*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

A series of new podands consisting of 2,6-cis-diaryl-1,3,5,7- tetraoxadecalin systems 2-7 have been prepared and fully characterized; the crystal structure of (2R,6R,9S; 9,10-P)-cis-2,6-di(p-nitrophenyl)1,3,5,7- tetraoxadecalin 4 showed characterized 'host-guest' packing and structural data which fitted well with the stereoelectronic features of the cis-1,3,5,7-tod system and a new class of macro-cyclophanes (9, 10) was unravelled.

Original languageEnglish
Pages (from-to)1611-1612
Number of pages2
JournalChemical Communications
Issue number13
DOIs
StatePublished - 1994

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