TY - JOUR
T1 - New lanthanide sulfate-oxalate hybrid solids containing different inorganic building blocks
AU - Wang, Kangcai
AU - Wang, Yu
AU - Xu, Dingguo
AU - Luo, Daibing
AU - Lin, Zhien
N1 - Funding Information:
This work was supported by the SRF for ROCS, SEM (Z. L., 20111139-10-3 ) and the Program for New Century Excellent Talents in University (D. X., NCET-10-0606 ).
PY - 2013
Y1 - 2013
N2 - Three new lanthanide sulfate-oxalate hybrid solids, Er2(SO 4)(C2O4)2(H2O) 6·0.5H2O (1), Nd3(SO4)(C 2O4)3.5(H2O)7· H2O (2), and [C4H14N2] 0.5·Nd2(SO4)2(C 2O4)1.5(H2O)4 (3), have been synthesized and structurally characterized. Compound 1 has a rare ladder-like structure, while compounds 2 and 3 have different three-dimensional structures. The presence of large 12-ring channels in the structure of 3 is noteworthy. The powder X-ray diffraction, IR spectra, thermogravimetric analyses, and magnetic susceptibility measurements of compounds 1 and 2 have also been investigated.
AB - Three new lanthanide sulfate-oxalate hybrid solids, Er2(SO 4)(C2O4)2(H2O) 6·0.5H2O (1), Nd3(SO4)(C 2O4)3.5(H2O)7· H2O (2), and [C4H14N2] 0.5·Nd2(SO4)2(C 2O4)1.5(H2O)4 (3), have been synthesized and structurally characterized. Compound 1 has a rare ladder-like structure, while compounds 2 and 3 have different three-dimensional structures. The presence of large 12-ring channels in the structure of 3 is noteworthy. The powder X-ray diffraction, IR spectra, thermogravimetric analyses, and magnetic susceptibility measurements of compounds 1 and 2 have also been investigated.
KW - Hybrid solid
KW - Hydrothermal synthesis
KW - Lanthanide
KW - Sulfate Oxalate
UR - http://www.scopus.com/inward/record.url?scp=84884474854&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2013.08.040
DO - 10.1016/j.inoche.2013.08.040
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AN - SCOPUS:84884474854
SN - 1387-7003
VL - 36
SP - 146
EP - 149
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
ER -