TY - JOUR
T1 - New insights into the mechanism of fast intramolecular electron transfer
AU - Huppert, Dan
AU - Ittah, Varda
AU - Kosower, Edward M.
PY - 1988/2/12
Y1 - 1988/2/12
N2 - Activationless, solvent-controlled fast intramolecular electron transfer (ET) rate constants are reported for three N-arylaminonaphthalenesulfon-N,N-dimethylamides over a wide temperature range. The conversion of the initial S1,np state into the S1,ct state (by a two-state mechanism) is confirmed by time-resolved spectroscopy for which appropriate simulations can be constructed.
AB - Activationless, solvent-controlled fast intramolecular electron transfer (ET) rate constants are reported for three N-arylaminonaphthalenesulfon-N,N-dimethylamides over a wide temperature range. The conversion of the initial S1,np state into the S1,ct state (by a two-state mechanism) is confirmed by time-resolved spectroscopy for which appropriate simulations can be constructed.
UR - http://www.scopus.com/inward/record.url?scp=0042949397&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(88)87082-9
DO - 10.1016/0009-2614(88)87082-9
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AN - SCOPUS:0042949397
SN - 0009-2614
VL - 144
SP - 15
EP - 23
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1
ER -