New generation of ordered polymer electrolytes for lithium batteries

D. Golodnitsky; E. Livshits; R. Kovarsky; E. Peled; S. H. Chung; S. Suarez; S. G. Greenbaum

doi:10.1149/1.1803434

New generation of ordered polymer electrolytes for lithium batteries

D. Golodnitsky^*, E. Livshits, R. Kovarsky, E. Peled, S. H. Chung, S. Suarez, S. G. Greenbaum

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In poly(ethylene oxide)-based solid electrolytes, ionic conduction can occur by cations moving inside the helix (along the helix axis) and by anions moving on its envelope. This particular mode of ion transport can be enhanced by alignment of the polymeric structural units. We describe a procedure for orienting the helices in the perpendicular direction, the result of which is a one-order-of-magnitude increase in polymer electrolyte (PE) conductivity and a similar decrease in PE/electrode interphase resistance. This procedure could also be of importance in the orientation of polymers in the nanoscale for various applications.

Original language	English
Pages (from-to)	A412-A415
Journal	Electrochemical and Solid-State Letters
Volume	7
Issue number	11
DOIs	https://doi.org/10.1149/1.1803434
State	Published - 2004

Access to Document

10.1149/1.1803434

Cite this

@article{424393749e7140c7930fd239d3fcf899,

title = "New generation of ordered polymer electrolytes for lithium batteries",

abstract = "In poly(ethylene oxide)-based solid electrolytes, ionic conduction can occur by cations moving inside the helix (along the helix axis) and by anions moving on its envelope. This particular mode of ion transport can be enhanced by alignment of the polymeric structural units. We describe a procedure for orienting the helices in the perpendicular direction, the result of which is a one-order-of-magnitude increase in polymer electrolyte (PE) conductivity and a similar decrease in PE/electrode interphase resistance. This procedure could also be of importance in the orientation of polymers in the nanoscale for various applications.",

author = "D. Golodnitsky and E. Livshits and R. Kovarsky and E. Peled and Chung, {S. H.} and S. Suarez and Greenbaum, {S. G.}",

year = "2004",

doi = "10.1149/1.1803434",

language = "אנגלית",

volume = "7",

pages = "A412--A415",

journal = "Electrochemical and Solid-State Letters",

issn = "1099-0062",

publisher = "Electrochemical Society",

number = "11",

}

TY - JOUR

T1 - New generation of ordered polymer electrolytes for lithium batteries

AU - Golodnitsky, D.

AU - Livshits, E.

AU - Kovarsky, R.

AU - Peled, E.

AU - Chung, S. H.

AU - Suarez, S.

AU - Greenbaum, S. G.

PY - 2004

Y1 - 2004

N2 - In poly(ethylene oxide)-based solid electrolytes, ionic conduction can occur by cations moving inside the helix (along the helix axis) and by anions moving on its envelope. This particular mode of ion transport can be enhanced by alignment of the polymeric structural units. We describe a procedure for orienting the helices in the perpendicular direction, the result of which is a one-order-of-magnitude increase in polymer electrolyte (PE) conductivity and a similar decrease in PE/electrode interphase resistance. This procedure could also be of importance in the orientation of polymers in the nanoscale for various applications.

AB - In poly(ethylene oxide)-based solid electrolytes, ionic conduction can occur by cations moving inside the helix (along the helix axis) and by anions moving on its envelope. This particular mode of ion transport can be enhanced by alignment of the polymeric structural units. We describe a procedure for orienting the helices in the perpendicular direction, the result of which is a one-order-of-magnitude increase in polymer electrolyte (PE) conductivity and a similar decrease in PE/electrode interphase resistance. This procedure could also be of importance in the orientation of polymers in the nanoscale for various applications.

UR - http://www.scopus.com/inward/record.url?scp=10044242483&partnerID=8YFLogxK

U2 - 10.1149/1.1803434

DO - 10.1149/1.1803434

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:10044242483

SN - 1099-0062

VL - 7

SP - A412-A415

JO - Electrochemical and Solid-State Letters

JF - Electrochemical and Solid-State Letters

IS - 11

ER -

New generation of ordered polymer electrolytes for lithium batteries

Abstract

Access to Document

Other files and links

Fingerprint

Cite this