TY - JOUR
T1 - N 2-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N 2,N 7,N 7-triphenyl-9H-fluorene-2,7-diamine
AU - Baheti, Abhishek
AU - Thomas, K. R.Justin
AU - Ng, Seik Weng
AU - Tiekink, Edward R.T.
PY - 2012/3
Y1 - 2012/3
N2 - In the title mol-ecule, C 51H 46BrN 3, the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C - H⋯π inter-actions. The butyl substituent is disordered with two sites resolved for the terminal propyl atoms; the major component had a site-occupancy factor of 0.686 (3).
AB - In the title mol-ecule, C 51H 46BrN 3, the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C - H⋯π inter-actions. The butyl substituent is disordered with two sites resolved for the terminal propyl atoms; the major component had a site-occupancy factor of 0.686 (3).
KW - R factor = 0.044
KW - T = 100 K
KW - data-to-parameter ratio = 16.2
KW - disorder in main residue
KW - mean σ(C-C) = 0.003 Å
KW - single-crystal X-ray study
KW - wR factor = 0.112
UR - http://www.scopus.com/inward/record.url?scp=84857936078&partnerID=8YFLogxK
U2 - 10.1107/S160053681200791X
DO - 10.1107/S160053681200791X
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AN - SCOPUS:84857936078
SN - 1600-5368
VL - 68
SP - o860-o861
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 3
ER -