Morphological effects in conducting polymer films studied by combined OCM and spectroscopic ellipsometry

E. Sabatani; E. Ticianelli; A. Redondo; I. Rubinstein; J. Rishpon; S. Gottesfeld

doi:10.1016/0379-6779(93)90240-W

Morphological effects in conducting polymer films studied by combined OCM and spectroscopic ellipsometry

E. Sabatani^*, E. Ticianelli, A. Redondo, I. Rubinstein, J. Rishpon, S. Gottesfeld

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

This contribution describes our studies of electrochemically grown conducting polymer (CP) films. We used an instrumental system which enables simultaneous optical (ellipsometric) and microgravimetric (Quartz-Crystal-Microbalance) measurements in situ during CP film growth and during electrochemical cycling. Our paper reviews recent results obtained with this system in the study of films of polyaniline and of polypyrrole in aqueous systems which provides information on film growth mechanisms and on the dependence of film morphology on electrochemical growth conditions and postgrowth treatments. We describe recent measurements of morphological changes in electrochemically grown films of polyaniline induced by the application of electrochemical undoping-redoping cycles.

Original language	English
Pages (from-to)	1293-1298
Number of pages	6
Journal	Synthetic Metals
Volume	55
Issue number	2-3
DOIs	https://doi.org/10.1016/0379-6779(93)90240-W
State	Published - 22 Mar 1993
Externally published	Yes

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title = "Morphological effects in conducting polymer films studied by combined OCM and spectroscopic ellipsometry",

abstract = "This contribution describes our studies of electrochemically grown conducting polymer (CP) films. We used an instrumental system which enables simultaneous optical (ellipsometric) and microgravimetric (Quartz-Crystal-Microbalance) measurements in situ during CP film growth and during electrochemical cycling. Our paper reviews recent results obtained with this system in the study of films of polyaniline and of polypyrrole in aqueous systems which provides information on film growth mechanisms and on the dependence of film morphology on electrochemical growth conditions and postgrowth treatments. We describe recent measurements of morphological changes in electrochemically grown films of polyaniline induced by the application of electrochemical undoping-redoping cycles.",

author = "E. Sabatani and E. Ticianelli and A. Redondo and I. Rubinstein and J. Rishpon and S. Gottesfeld",

note = "Funding Information: ACKNOWLEDGEMENT This work was supported by the Advanced Industrial Materials Department of Energy.",

year = "1993",

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doi = "10.1016/0379-6779(93)90240-W",

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T1 - Morphological effects in conducting polymer films studied by combined OCM and spectroscopic ellipsometry

AU - Sabatani, E.

AU - Ticianelli, E.

AU - Redondo, A.

AU - Rubinstein, I.

AU - Rishpon, J.

AU - Gottesfeld, S.

N1 - Funding Information: ACKNOWLEDGEMENT This work was supported by the Advanced Industrial Materials Department of Energy.

PY - 1993/3/22

Y1 - 1993/3/22

N2 - This contribution describes our studies of electrochemically grown conducting polymer (CP) films. We used an instrumental system which enables simultaneous optical (ellipsometric) and microgravimetric (Quartz-Crystal-Microbalance) measurements in situ during CP film growth and during electrochemical cycling. Our paper reviews recent results obtained with this system in the study of films of polyaniline and of polypyrrole in aqueous systems which provides information on film growth mechanisms and on the dependence of film morphology on electrochemical growth conditions and postgrowth treatments. We describe recent measurements of morphological changes in electrochemically grown films of polyaniline induced by the application of electrochemical undoping-redoping cycles.

AB - This contribution describes our studies of electrochemically grown conducting polymer (CP) films. We used an instrumental system which enables simultaneous optical (ellipsometric) and microgravimetric (Quartz-Crystal-Microbalance) measurements in situ during CP film growth and during electrochemical cycling. Our paper reviews recent results obtained with this system in the study of films of polyaniline and of polypyrrole in aqueous systems which provides information on film growth mechanisms and on the dependence of film morphology on electrochemical growth conditions and postgrowth treatments. We describe recent measurements of morphological changes in electrochemically grown films of polyaniline induced by the application of electrochemical undoping-redoping cycles.

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JO - Synthetic Metals

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Morphological effects in conducting polymer films studied by combined OCM and spectroscopic ellipsometry

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