Molecular complexes of I2: A Mössbauer effect study

S. Bukshpan; C. Goldstein; T. Sonnino; L. May; M. Pasternak

doi:10.1063/1.430844

Molecular complexes of I₂: A Mössbauer effect study

S. Bukshpan^*, C. Goldstein, T. Sonnino, L. May, M. Pasternak

^*Corresponding author for this work

School of Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

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Abstract

Molecular complexes of I₂ with different organic solvents, in frozen solution, were studied using Mössbauer effect in ¹²⁹I. The results obtained for the hyperfine constants indicate that the complexes may be divided into three main groups with increasing bond strength, according to the organic solvent used: (a) π solvents, (b) alcohols and ether, and (c) amines. The same classification was also used in the analyasis of various properties of the I₂ complexes. Some general conclusions on the electronic nature of the I₂-complexant bond are derived and discussed.

Original language	English
Pages (from-to)	2606-2609
Number of pages	4
Journal	The Journal of Chemical Physics
Volume	62
Issue number	7
DOIs	https://doi.org/10.1063/1.430844
State	Published - 1975

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abstract = "Molecular complexes of I2 with different organic solvents, in frozen solution, were studied using M{\"o}ssbauer effect in 129I. The results obtained for the hyperfine constants indicate that the complexes may be divided into three main groups with increasing bond strength, according to the organic solvent used: (a) π solvents, (b) alcohols and ether, and (c) amines. The same classification was also used in the analyasis of various properties of the I2 complexes. Some general conclusions on the electronic nature of the I2-complexant bond are derived and discussed.",

author = "S. Bukshpan and C. Goldstein and T. Sonnino and L. May and M. Pasternak",

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AU - Pasternak, M.

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AB - Molecular complexes of I2 with different organic solvents, in frozen solution, were studied using Mössbauer effect in 129I. The results obtained for the hyperfine constants indicate that the complexes may be divided into three main groups with increasing bond strength, according to the organic solvent used: (a) π solvents, (b) alcohols and ether, and (c) amines. The same classification was also used in the analyasis of various properties of the I2 complexes. Some general conclusions on the electronic nature of the I2-complexant bond are derived and discussed.

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Molecular complexes of I₂: A Mössbauer effect study

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