TY - JOUR
T1 - Microscopic solvation effects on pure radiative lifetimes of large molecules in heteroclusters
AU - Shalev, Eli
AU - Jortner, Joshua
PY - 1991/3/15
Y1 - 1991/3/15
N2 - We advance a theory of microscopic solvent perturbations of pure radiative lifetimes, τr, of (aromatic) · (inert-gas)n heteroclusters, which originate from intermolecular interactions between molecular multicentre transition monopoles and atomic point transition dipoles. This theory accounts well for the experimental τr data of the S1 state of 9,10-dichloroanthracene·R (RAr, Kr, Xe) heteroclusters. τr is expected to serve as a useful probe for the interrogation of structure and dynamics of isomerization in heteroclusters.
AB - We advance a theory of microscopic solvent perturbations of pure radiative lifetimes, τr, of (aromatic) · (inert-gas)n heteroclusters, which originate from intermolecular interactions between molecular multicentre transition monopoles and atomic point transition dipoles. This theory accounts well for the experimental τr data of the S1 state of 9,10-dichloroanthracene·R (RAr, Kr, Xe) heteroclusters. τr is expected to serve as a useful probe for the interrogation of structure and dynamics of isomerization in heteroclusters.
UR - http://www.scopus.com/inward/record.url?scp=4243492803&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(91)85048-2
DO - 10.1016/0009-2614(91)85048-2
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:4243492803
SN - 0009-2614
VL - 178
SP - 31
EP - 35
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1
ER -