TY - JOUR
T1 - Microscale simulation of particle deposition in porous media
AU - Boccardo, Gianluca
AU - Marchisio, Daniele L.
AU - Sethi, Rajandrea
N1 - Funding Information:
This work was financially supported by the EU research project AQUAREHAB (FP7, Grant Agreement No. 226565) and by the Italian Ministry of Research and Higher Education through the PRIN project 2008 “ Disaggregazione, stabilizzazione e trasporto di ferro zerovalente nanoscopico (NZVI)”. The contributions of Francesca Messina and Matteo Icardi are also gratefully acknowledged.
PY - 2014/3/1
Y1 - 2014/3/1
N2 - In this work several geometries, each representing a different porous medium, are considered to perform detailed computational fluid dynamics simulation for fluid flow, particle transport and deposition. Only Brownian motions and steric interception are accounted for as deposition mechanisms. Firstly pressure drop in each porous medium is analyzed in order to determine an effective grain size, by fitting the results with the Ergun law. Then grid independence is assessed. Lastly, particle transport in the system is investigated via Eulerian steady-state simulations, where particle concentration is solved for, not following explicitly particles' trajectories, but solving the corresponding advection-diffusion equation. An assumption was made in considering favorable collector-particle interactions, resulting in a "perfect sink" boundary condition for the collectors. The gathered simulation data are used to calculate the deposition efficiency due to Brownian motions and steric interception. The original Levich law for one simple circular collector is verified; subsequently porous media constituted by a packing of collectors are scrutinized. Results show that the interactions between the different collectors result in behaviors which are not in line with the theory developed by Happel and co-workers, highlighting a different dependency of the deposition efficiency on the dimensionless groups involved in the relevant correlations.
AB - In this work several geometries, each representing a different porous medium, are considered to perform detailed computational fluid dynamics simulation for fluid flow, particle transport and deposition. Only Brownian motions and steric interception are accounted for as deposition mechanisms. Firstly pressure drop in each porous medium is analyzed in order to determine an effective grain size, by fitting the results with the Ergun law. Then grid independence is assessed. Lastly, particle transport in the system is investigated via Eulerian steady-state simulations, where particle concentration is solved for, not following explicitly particles' trajectories, but solving the corresponding advection-diffusion equation. An assumption was made in considering favorable collector-particle interactions, resulting in a "perfect sink" boundary condition for the collectors. The gathered simulation data are used to calculate the deposition efficiency due to Brownian motions and steric interception. The original Levich law for one simple circular collector is verified; subsequently porous media constituted by a packing of collectors are scrutinized. Results show that the interactions between the different collectors result in behaviors which are not in line with the theory developed by Happel and co-workers, highlighting a different dependency of the deposition efficiency on the dimensionless groups involved in the relevant correlations.
KW - Brownian deposition
KW - CFD
KW - Nanoparticle deposition
KW - Pore-scale simulation
KW - Porous media
KW - Steric interception
UR - http://www.scopus.com/inward/record.url?scp=84890195092&partnerID=8YFLogxK
U2 - 10.1016/j.jcis.2013.11.007
DO - 10.1016/j.jcis.2013.11.007
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AN - SCOPUS:84890195092
SN - 0021-9797
VL - 417
SP - 227
EP - 237
JO - Journal of Colloid and Interface Science
JF - Journal of Colloid and Interface Science
ER -