TY - JOUR
T1 - Micropatterning of metallopolymers
T2 - Syntheses of back-to-back coupled octylated 2,6-Bis(pyrazolyl)pyridine ligands and their solution-processable coordination polymers
AU - Basak, Supratim
AU - Hui, Pramiti
AU - Boodida, Sathyanarayana
AU - Chandrasekar, Rajadurai
PY - 2012/4/6
Y1 - 2012/4/6
N2 - This paper presents a 10-step synthetic route for the preparation of a series of new back-to-back coupled 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligands (L0-L3) decorated with tetraoctyl chains. Ligand L1 self-assembles with Zn 2+ ion to form a highly soluble metallo-supramolecular polymer 1 with M n ∼ 9600 g/mol. To demonstrate the processability of polymer 1, by following a "top-down" approach periodic one-dimensional fluorescent microstripes were fabricated on a silica substrate.
AB - This paper presents a 10-step synthetic route for the preparation of a series of new back-to-back coupled 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligands (L0-L3) decorated with tetraoctyl chains. Ligand L1 self-assembles with Zn 2+ ion to form a highly soluble metallo-supramolecular polymer 1 with M n ∼ 9600 g/mol. To demonstrate the processability of polymer 1, by following a "top-down" approach periodic one-dimensional fluorescent microstripes were fabricated on a silica substrate.
UR - http://www.scopus.com/inward/record.url?scp=84859582406&partnerID=8YFLogxK
U2 - 10.1021/jo300050m
DO - 10.1021/jo300050m
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C2 - 22417165
AN - SCOPUS:84859582406
SN - 0022-3263
VL - 77
SP - 3620
EP - 3626
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 7
ER -