Methanol Reduces an Organopalladium(II) Complex to a Palladium(] Hydride. Crystallographic Characterization of a Hydrido-Bridged Palladium Complex

Moshe Portnoy; Felix Frolow; David Milstein

doi:10.1021/om00058a007

Methanol Reduces an Organopalladium(II) Complex to a Palladium(] Hydride. Crystallographic Characterization of a Hydrido-Bridged Palladium Complex

Moshe Portnoy, Felix Frolow, David Milstein^*

^*Corresponding author for this work

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

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Abstract

The organopalladium(II) complex 1 is reduced by methanol to the hydrido-bridged Pd(I) complex 2, which was crystallographically characterized. A mechanism involving electrophilic attack of a cationic palladium hydride intermediate on a Pd(0) carbonyl complex is indicated.

Original language	English
Pages (from-to)	3960-3962
Number of pages	3
Journal	Organometallics
Volume	10
Issue number	12
DOIs	https://doi.org/10.1021/om00058a007
State	Published - 1 Dec 1991
Externally published	Yes

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title = "Methanol Reduces an Organopalladium(II) Complex to a Palladium(] Hydride. Crystallographic Characterization of a Hydrido-Bridged Palladium Complex",

abstract = "The organopalladium(II) complex 1 is reduced by methanol to the hydrido-bridged Pd(I) complex 2, which was crystallographically characterized. A mechanism involving electrophilic attack of a cationic palladium hydride intermediate on a Pd(0) carbonyl complex is indicated.",

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AU - Milstein, David

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N2 - The organopalladium(II) complex 1 is reduced by methanol to the hydrido-bridged Pd(I) complex 2, which was crystallographically characterized. A mechanism involving electrophilic attack of a cationic palladium hydride intermediate on a Pd(0) carbonyl complex is indicated.

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Methanol Reduces an Organopalladium(II) Complex to a Palladium(] Hydride. Crystallographic Characterization of a Hydrido-Bridged Palladium Complex

Abstract

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