Methanol Reduces an Organopalladium(II) Complex to a Palladium(] Hydride. Crystallographic Characterization of a Hydrido-Bridged Palladium Complex

Moshe Portnoy, Felix Frolow, David Milstein*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

The organopalladium(II) complex 1 is reduced by methanol to the hydrido-bridged Pd(I) complex 2, which was crystallographically characterized. A mechanism involving electrophilic attack of a cationic palladium hydride intermediate on a Pd(0) carbonyl complex is indicated.

Original languageEnglish
Pages (from-to)3960-3962
Number of pages3
JournalOrganometallics
Volume10
Issue number12
DOIs
StatePublished - 1 Dec 1991
Externally publishedYes

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