Metal-organic coordination polymers with a new 3,5-(4-carboxybenzyloxy) benzoic acid linker

Ranjan Patra; Hatem M. Titi; Israel Goldberg

doi:10.1039/c3nj00054k

Metal-organic coordination polymers with a new 3,5-(4-carboxybenzyloxy) benzoic acid linker

Ranjan Patra, Hatem M. Titi, Israel Goldberg^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

New framework solids consisting of coordination polymers [Ce(L)(DMA)(H ₂O)]_n (1), [Nd(L)(DMA)(H₂O)]_n (2), [Cu₂(OH)(L)]_n (3) and [Cd₂(L) ₂(4,4′-bipyridyl)]_n·(CH₃NH ₂CH₃⁺)_2n (4) (H₃L = 3,5-(4-carboxybenzyloxy) benzoic acid; DMA = dimethyl acetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by X-ray crystallography. They reveal two-dimensional and three-dimensional network architectures. Thermal analysis (TGA and DTA) features of 1-4 and solid-state variable temperature magnetic susceptibility data of 2 and 3 are reported as well.

Original language	English
Pages (from-to)	1494-1500
Number of pages	7
Journal	New Journal of Chemistry
Volume	37
Issue number	5
DOIs	https://doi.org/10.1039/c3nj00054k
State	Published - May 2013

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title = "Metal-organic coordination polymers with a new 3,5-(4-carboxybenzyloxy) benzoic acid linker",

abstract = "New framework solids consisting of coordination polymers [Ce(L)(DMA)(H 2O)]n (1), [Nd(L)(DMA)(H2O)]n (2), [Cu2(OH)(L)]n (3) and [Cd2(L) 2(4,4′-bipyridyl)]n·(CH3NH 2CH3+)2n (4) (H3L = 3,5-(4-carboxybenzyloxy) benzoic acid; DMA = dimethyl acetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by X-ray crystallography. They reveal two-dimensional and three-dimensional network architectures. Thermal analysis (TGA and DTA) features of 1-4 and solid-state variable temperature magnetic susceptibility data of 2 and 3 are reported as well.",

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doi = "10.1039/c3nj00054k",

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AU - Patra, Ranjan

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AU - Goldberg, Israel

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N2 - New framework solids consisting of coordination polymers [Ce(L)(DMA)(H 2O)]n (1), [Nd(L)(DMA)(H2O)]n (2), [Cu2(OH)(L)]n (3) and [Cd2(L) 2(4,4′-bipyridyl)]n·(CH3NH 2CH3+)2n (4) (H3L = 3,5-(4-carboxybenzyloxy) benzoic acid; DMA = dimethyl acetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by X-ray crystallography. They reveal two-dimensional and three-dimensional network architectures. Thermal analysis (TGA and DTA) features of 1-4 and solid-state variable temperature magnetic susceptibility data of 2 and 3 are reported as well.

AB - New framework solids consisting of coordination polymers [Ce(L)(DMA)(H 2O)]n (1), [Nd(L)(DMA)(H2O)]n (2), [Cu2(OH)(L)]n (3) and [Cd2(L) 2(4,4′-bipyridyl)]n·(CH3NH 2CH3+)2n (4) (H3L = 3,5-(4-carboxybenzyloxy) benzoic acid; DMA = dimethyl acetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by X-ray crystallography. They reveal two-dimensional and three-dimensional network architectures. Thermal analysis (TGA and DTA) features of 1-4 and solid-state variable temperature magnetic susceptibility data of 2 and 3 are reported as well.

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Metal-organic coordination polymers with a new 3,5-(4-carboxybenzyloxy) benzoic acid linker

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