TY - JOUR
T1 - Mechanism of collision-induced intersystem crossing in CO
AU - Grimbert, D.
AU - Lavollée, M.
AU - Nitzan, A.
AU - Tramer, A.
N1 - Funding Information:
The authors are highly indebted to the team of the LURE and of the Linear Accelerator Laboratory in &say whose work made possible our experiments. Thanks are also due to Drs. G. Bergeron, K.F. Freed and C_ Tric for discussions and remarks. One of us (AN) thanks the Commission for Basic Research of the Israel Academy of Science for supporting this work and the France-israel Scientists Exchange Program for a travel grant.
PY - 1978/7/1
Y1 - 1978/7/1
N2 - We have studied inert-gas pressure effects on the fluorescence decay in CO selectively excited to the υ = 0 to 7 vibronic levels of the A 1Π electronic state. It is shown that the dependence of the quenching cross section σisc on the average value of the ST mixing coefficient (β2) has a quasi-logarithmic form. A simple two-level model describing semiquantitatively this behavior is proposed.
AB - We have studied inert-gas pressure effects on the fluorescence decay in CO selectively excited to the υ = 0 to 7 vibronic levels of the A 1Π electronic state. It is shown that the dependence of the quenching cross section σisc on the average value of the ST mixing coefficient (β2) has a quasi-logarithmic form. A simple two-level model describing semiquantitatively this behavior is proposed.
UR - http://www.scopus.com/inward/record.url?scp=4244005506&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(78)80348-0
DO - 10.1016/0009-2614(78)80348-0
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AN - SCOPUS:4244005506
SN - 0009-2614
VL - 57
SP - 45
EP - 49
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1
ER -