@article{4ae7e902454c414aa3b9a02a0f419fd9,
title = "Low-cost open-space scaffold structure for high-capacity silicon anode",
abstract = "One of the causes of capacity fading in cells containing silicon anodes is the growth of a secondary SEI. A possible way of solving this problem is to create an anode with a highly porous three-dimensional structure, in which the growing SEI could be accommodated without blocking conduction pathways inside the anode. We evaluated this approach by building a 3D carbon-fiber (CF) scaffold matrix made by the pyrolysis of cotton wool. Anodes fabricated from bare and carbon-coated silicon nanoparticles, were studied from the viewpoint of the influence of anode structure and LixSi phase transformations on prolonged cycling of Li/Si cells. Analysis of the mechanisms of degradation of silicon anodes in lithium-ion batteries provides possible ways of elimination of the negative effect of the growth of the SEI on capacity fading. It will be noted that all the anodes containing cotton-carbon fiber matrix exhibit much more stable cycle life than do CF-free anodes. The synthesis of the carbon-fiber (CF) scaffold matrix is simple and easy to scale up to industrial production.",
author = "N. Aloni and D. Golodnitsky and E. Peled",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = jun,
doi = "10.1016/j.ssi.2018.02.011",
language = "אנגלית",
volume = "319",
pages = "228--233",
journal = "Solid State Ionics",
issn = "0167-2738",
publisher = "Elsevier B.V.",
}