ITIES fluctuations induced by easily transferable ions

L. I. Daikhin, A. A. Kornyshev*, A. M. Kuznetsov, M. Urbakh

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

We develop a theory of undulations of the interface between two immiscible electrolyte solutions, caused by a minute concentration of ions with low free energy of transfer that are able to trespass the interface under a small potential bias. We derive simple expressions for the correlation function of the interfacial undulations and their mean square height as a function of concentration of these easily transferable ions and the ionic current across the interface. Possible experiments for verifying these predictions are discussed, as well as what we could learn from them for a more detailed understanding of the properties of ITIES.

Original languageEnglish
Pages (from-to)253-260
Number of pages8
JournalChemical Physics
Volume319
Issue number1-3
DOIs
StatePublished - 7 Dec 2005

Funding

FundersFunder number
Leverhulme TrustF/07 058/P

    Keywords

    • ITIES
    • Ion transfer
    • Liquid-liquid interfaces
    • Surface fluctuations

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