Isolated ultracold porphyrins in supersonic expansions. II. Zn-tetrabenzoporphyrin

Uzi Even; Jacob Magen; Joshua Jortner; Joel Friedman

doi:10.1063/1.444439

Isolated ultracold porphyrins in supersonic expansions. II. Zn-tetrabenzoporphyrin

Uzi Even^*, Jacob Magen, Joshua Jortner, Joel Friedman

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Laser-induced fluorescence excitation spectra of zinc tetrabenzoporphyrin in seeded, pulsed, supersonic expansions of He reveal well-resolved vibrational excitations for the S₀→S₁ and S₀→ S₂ electronic transitions. Electronic relaxation in the S₁ manifold was interrogated by time-resolved spectroscopy, exhibiting a practical independence of the lifetimes on the excess vibrational energies in the range E_v = 0-10000 cm^-1. Spectroscopic line broadening data provided semiquantitative information on interstate electronic relaxation from the electronic origin of the S₂ state, whose lifetime is τ(S ₂) > 4 ps.

Original language	English
Pages (from-to)	4384-4390
Number of pages	7
Journal	The Journal of Chemical Physics
Volume	77
Issue number	9
DOIs	https://doi.org/10.1063/1.444439
State	Published - 1982

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abstract = "Laser-induced fluorescence excitation spectra of zinc tetrabenzoporphyrin in seeded, pulsed, supersonic expansions of He reveal well-resolved vibrational excitations for the S0→S1 and S0→ S2 electronic transitions. Electronic relaxation in the S1 manifold was interrogated by time-resolved spectroscopy, exhibiting a practical independence of the lifetimes on the excess vibrational energies in the range Ev = 0-10000 cm-1. Spectroscopic line broadening data provided semiquantitative information on interstate electronic relaxation from the electronic origin of the S2 state, whose lifetime is τ(S 2) > 4 ps.",

author = "Uzi Even and Jacob Magen and Joshua Jortner and Joel Friedman",

year = "1982",

doi = "10.1063/1.444439",

language = "אנגלית",

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AU - Magen, Jacob

AU - Jortner, Joshua

AU - Friedman, Joel

PY - 1982

Y1 - 1982

N2 - Laser-induced fluorescence excitation spectra of zinc tetrabenzoporphyrin in seeded, pulsed, supersonic expansions of He reveal well-resolved vibrational excitations for the S0→S1 and S0→ S2 electronic transitions. Electronic relaxation in the S1 manifold was interrogated by time-resolved spectroscopy, exhibiting a practical independence of the lifetimes on the excess vibrational energies in the range Ev = 0-10000 cm-1. Spectroscopic line broadening data provided semiquantitative information on interstate electronic relaxation from the electronic origin of the S2 state, whose lifetime is τ(S 2) > 4 ps.

AB - Laser-induced fluorescence excitation spectra of zinc tetrabenzoporphyrin in seeded, pulsed, supersonic expansions of He reveal well-resolved vibrational excitations for the S0→S1 and S0→ S2 electronic transitions. Electronic relaxation in the S1 manifold was interrogated by time-resolved spectroscopy, exhibiting a practical independence of the lifetimes on the excess vibrational energies in the range Ev = 0-10000 cm-1. Spectroscopic line broadening data provided semiquantitative information on interstate electronic relaxation from the electronic origin of the S2 state, whose lifetime is τ(S 2) > 4 ps.

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ER -

Isolated ultracold porphyrins in supersonic expansions. II. Zn-tetrabenzoporphyrin

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