TY - JOUR
T1 - Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts
AU - Livshits-Kritsman, Yulia
AU - Tumanskii, Boris
AU - Ménard, Gabriel
AU - Dobrovetsky, Roman
N1 - Publisher Copyright:
This journal is © The Royal Society of Chemistry.
PY - 2020
Y1 - 2020
N2 - Phosphonyl radicals ([R2PO]) and their adducts are proposed as intermediates in a number of important chemical and biological processes. Despite the great interest in these species, there are no examples of stable, isolated phosphonyl radicals or their adducts reported in the literature. Here we report the synthesis, EPR and theoretical study of stable, isolable cyclic (alkyl)(amino)carbene (cAAC)-phosphonyl radical adducts, [cAAC-P(O)R2] (R = OPri, Ph).
AB - Phosphonyl radicals ([R2PO]) and their adducts are proposed as intermediates in a number of important chemical and biological processes. Despite the great interest in these species, there are no examples of stable, isolated phosphonyl radicals or their adducts reported in the literature. Here we report the synthesis, EPR and theoretical study of stable, isolable cyclic (alkyl)(amino)carbene (cAAC)-phosphonyl radical adducts, [cAAC-P(O)R2] (R = OPri, Ph).
UR - http://www.scopus.com/inward/record.url?scp=85078692425&partnerID=8YFLogxK
U2 - 10.1039/c9cc09244g
DO - 10.1039/c9cc09244g
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C2 - 31912813
AN - SCOPUS:85078692425
SN - 1359-7345
VL - 56
SP - 1341
EP - 1344
JO - Chemical Communications
JF - Chemical Communications
IS - 9
ER -