Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand

Michaela Ritter, Anat Molad, Varun Rawat, Arkadi Vigalok*, Christian Limberg

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis and characterisation of an asymmetrically substituted calix-triazole ligand are reported. The ligand reacts with the Fe(II) precursor Fe2Mes4 to yield an iron(II) calixarene complex that is oxidised by dioxygen to provide a dinuclear Fe(III) compound featuring an oxido bridge.

Original languageEnglish
Pages (from-to)530-537
Number of pages8
JournalSupramolecular Chemistry
Volume26
Issue number7-8
DOIs
StatePublished - 3 Aug 2014

Keywords

  • calixarene
  • cross-coupling
  • metal complexes
  • triazole

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