Abstract
The fluorescence intensity of phosphorus corroles increases upon meso-Aryl C-F/C-H and P-OH/P-F substitutions, the latter affects corrole-centered redox processes more than C-H/C-F substitution on the corrole's skeleton, and the presence of F atoms allows for the first experimental insight into the electronic structures of oxidized corroles. Experimental and theoretical methodologies reveal that mono-but not bis-chlorosulfonation of the corrole skeleton is under kinetic control. Selective introduction of heavy atoms leads to complexes that are phosphorescent at room temperature.
Original language | English |
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Pages (from-to) | 6061-6067 |
Number of pages | 7 |
Journal | Inorganic Chemistry |
Volume | 55 |
Issue number | 12 |
DOIs | |
State | Published - 20 Jun 2016 |