Intermolecular VV transfer in the vibrational predissociation of some van der Waals dimers

J. A. Beswick*, Joshua Jortner

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

We explore the consequences of intermolecular vibrational energy transfer in the vibrational predissociation (VP) of linear AB...CD van der Waals dimers. On the basis of our energy gap law for VP, which are supported by numerical model calculations, we demonstrate the efficiency of the V → V + T process, which will be amenable to experimental observation.

Original languageEnglish
Pages (from-to)240-245
Number of pages6
JournalChemical Physics Letters
Volume65
Issue number2
DOIs
StatePublished - 15 Aug 1979

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