Hydration interactions: Aqueous solvent effects in electric double layers

Yoram Burak, David Andelman

Research output: Contribution to journalArticlepeer-review

Abstract

Ionic solutions with an attractive short-range pair interactions between the ions were modeled. A quadratic nonlocal term was added to the Poisson-Boltzman (PB) free energy theory to account for the short-range interactions. Solvent effects in a planar electric double layer were studied. Counterion density was found to increase near the charged surfaces and decrease at larger distances.

Original languageEnglish
Pages (from-to)5296-5312
Number of pages17
JournalPhysical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Volume62
Issue number4 B
DOIs
StatePublished - Oct 2000

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