Group 13 element containing conformationally rigid “N-E-N” heteroatomic bridged [3.3](2,6)pyridinophanes (E = B, Al)

Deependra Bawari; Chandrakala Negi; Kuldeep Jaiswal; Billa Prashanth; Angshuman Roy Choudhury; Sanjay Singh

doi:10.1039/c8cc05154b

Group 13 element containing conformationally rigid “N-E-N” heteroatomic bridged [3.3](2,6)pyridinophanes (E = B, Al)

Deependra Bawari, Chandrakala Negi, Kuldeep Jaiswal, Billa Prashanth, Angshuman Roy Choudhury, Sanjay Singh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The first examples of group 13 element containing pyridinophanes have been assembled using heteroatom N-E-N bridges (E = B, Al). The presence of B and Al as acceptor atoms in the bridges and their coordination with pyridine nitrogen has a very strong influence on the conformational rigidity of the pyridinophanes.

Original language	English
Pages (from-to)	8857-8860
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	64
DOIs	https://doi.org/10.1039/c8cc05154b
State	Published - 2018
Externally published	Yes

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abstract = "The first examples of group 13 element containing pyridinophanes have been assembled using heteroatom N-E-N bridges (E = B, Al). The presence of B and Al as acceptor atoms in the bridges and their coordination with pyridine nitrogen has a very strong influence on the conformational rigidity of the pyridinophanes.",

author = "Deependra Bawari and Chandrakala Negi and Kuldeep Jaiswal and Billa Prashanth and Choudhury, {Angshuman Roy} and Sanjay Singh",

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AU - Bawari, Deependra

AU - Negi, Chandrakala

AU - Jaiswal, Kuldeep

AU - Prashanth, Billa

AU - Choudhury, Angshuman Roy

AU - Singh, Sanjay

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2018

Y1 - 2018

N2 - The first examples of group 13 element containing pyridinophanes have been assembled using heteroatom N-E-N bridges (E = B, Al). The presence of B and Al as acceptor atoms in the bridges and their coordination with pyridine nitrogen has a very strong influence on the conformational rigidity of the pyridinophanes.

AB - The first examples of group 13 element containing pyridinophanes have been assembled using heteroatom N-E-N bridges (E = B, Al). The presence of B and Al as acceptor atoms in the bridges and their coordination with pyridine nitrogen has a very strong influence on the conformational rigidity of the pyridinophanes.

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Group 13 element containing conformationally rigid “N-E-N” heteroatomic bridged [3.3](2,6)pyridinophanes (E = B, Al)

Abstract

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