TY - JOUR
T1 - Geometrically Biased Homoconjugated Ketones. Synthetic Avenues to 1-Acyl-2,4-cyclohexadienes
AU - Fuchs, Benzion
AU - Zizuashvili, Jakob
AU - Abramson, Sarah
PY - 1982
Y1 - 1982
N2 - Synthetic approaches to a series of open (1), fused (2), and spiroannelated (3) 2,4-cyclohexadien-1-yl ketones, which differ in the geometrical juxtaposition of the homoconjugated chromophores, have been worked out. A series of prototropic rearrangements was found to occur, establishing an equilibrium between 28–30.
AB - Synthetic approaches to a series of open (1), fused (2), and spiroannelated (3) 2,4-cyclohexadien-1-yl ketones, which differ in the geometrical juxtaposition of the homoconjugated chromophores, have been worked out. A series of prototropic rearrangements was found to occur, establishing an equilibrium between 28–30.
UR - http://www.scopus.com/inward/record.url?scp=33845555420&partnerID=8YFLogxK
U2 - 10.1021/jo00139a018
DO - 10.1021/jo00139a018
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AN - SCOPUS:33845555420
SN - 0022-3263
VL - 47
SP - 3474
EP - 3477
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 18
ER -