TY - JOUR
T1 - Geminate recombination of proton transfer reactions
T2 - time-resolved fluorescence study of 1-naphthol-3,6-disulfonate
AU - Masad, A.
AU - Huppert, D.
N1 - Funding Information:
We are grateful to Professor P.M. Rentzepis, Dr. N. Agmon and Dr. E. Pines for discussions and suggestions. This work is supported, in part, by Grant 88-00125 from the United States Israel Binational Science Foundation and by a grant from the James Franck Binational German-Israeli Program in Laser-Matter Interaction.
PY - 1991/5/31
Y1 - 1991/5/31
N2 - Unlike the reversible proton recombination found in many excited-state proton transfer reactions, 1-naphthol-3,6-disulfonate exhibits an almost irreversible proton recombination process. As a result of quenching through geminate recombination, the fluorescence of the unprotonated form is nonexponential. The Debye-Smoluchowski equation is used to explain the effect of geminate recombination.
AB - Unlike the reversible proton recombination found in many excited-state proton transfer reactions, 1-naphthol-3,6-disulfonate exhibits an almost irreversible proton recombination process. As a result of quenching through geminate recombination, the fluorescence of the unprotonated form is nonexponential. The Debye-Smoluchowski equation is used to explain the effect of geminate recombination.
UR - http://www.scopus.com/inward/record.url?scp=0002928907&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(91)85141-I
DO - 10.1016/0009-2614(91)85141-I
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AN - SCOPUS:0002928907
SN - 0009-2614
VL - 180
SP - 409
EP - 415
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 5
ER -