From eilatin to isoeilatin: A skeletal rearrangement strongly influences π-stacking of Ru(II) complex

Sheba D. Bergman; Dvora Reshef; Limor Frish; Yoram Cohen; Israel Goldberg; Moshe Kol

doi:10.1021/ic049806g

From eilatin to isoeilatin: A skeletal rearrangement strongly influences π-stacking of Ru(II) complex

Sheba D. Bergman, Dvora Reshef, Limor Frish, Yoram Cohen, Israel Goldberg, Moshe Kol^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The C₁-symmetrical complex [Ru(bpy)₂(ieil)][PF ₆]₂ exhibits unique electrochemical and photophysical properties, and forms discrete dimers in solution and in the solid state held by weak π-π stacking interactions via its isoeilatin ligand, preferentially from one of its faces and in a specific orientation.

Original language	English
Pages (from-to)	3792-3794
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	13
DOIs	https://doi.org/10.1021/ic049806g
State	Published - 15 Jun 2004

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abstract = "The C1-symmetrical complex [Ru(bpy)2(ieil)][PF 6]2 exhibits unique electrochemical and photophysical properties, and forms discrete dimers in solution and in the solid state held by weak π-π stacking interactions via its isoeilatin ligand, preferentially from one of its faces and in a specific orientation.",

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AU - Frish, Limor

AU - Cohen, Yoram

AU - Goldberg, Israel

AU - Kol, Moshe

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AB - The C1-symmetrical complex [Ru(bpy)2(ieil)][PF 6]2 exhibits unique electrochemical and photophysical properties, and forms discrete dimers in solution and in the solid state held by weak π-π stacking interactions via its isoeilatin ligand, preferentially from one of its faces and in a specific orientation.

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JO - Inorganic Chemistry

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From eilatin to isoeilatin: A skeletal rearrangement strongly influences π-stacking of Ru(II) complex

Abstract

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