Flash photolysis of ammonia in the presence of oxygen

S. G. Cheskis; O. M. Sarkisov

doi:10.1016/0009-2614(79)80415-7

Flash photolysis of ammonia in the presence of oxygen

S. G. Cheskis^*, O. M. Sarkisov

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Flash photolysis of ammonia in the presence of oxygen was studied using the intracavity laser spectroscopy technique. The reaction NH₂ + O₂ was demonstrated to be of no importance and a value of k₆ < 1.5 × 10^-17 cm³/molecule s was estimate Accelerating NH₂ decay with oxygen addition is due to the reaction NH₂ + HO₂ and its rate constant was found to be k₇ = 2.5 × 10^-11 cm³/molecules.

Original language	English
Pages (from-to)	72-76
Number of pages	5
Journal	Chemical Physics Letters
Volume	62
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(79)80415-7
State	Published - 15 Mar 1979
Externally published	Yes

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title = "Flash photolysis of ammonia in the presence of oxygen",

abstract = "Flash photolysis of ammonia in the presence of oxygen was studied using the intracavity laser spectroscopy technique. The reaction NH2 + O2 was demonstrated to be of no importance and a value of k6 < 1.5 × 10-17 cm3/molecule s was estimate Accelerating NH2 decay with oxygen addition is due to the reaction NH2 + HO2 and its rate constant was found to be k7 = 2.5 × 10-11 cm3/molecules.",

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AB - Flash photolysis of ammonia in the presence of oxygen was studied using the intracavity laser spectroscopy technique. The reaction NH2 + O2 was demonstrated to be of no importance and a value of k6 < 1.5 × 10-17 cm3/molecule s was estimate Accelerating NH2 decay with oxygen addition is due to the reaction NH2 + HO2 and its rate constant was found to be k7 = 2.5 × 10-11 cm3/molecules.

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Flash photolysis of ammonia in the presence of oxygen

Abstract

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