Fixation of CO2 in bi-layered coordination networks of zinc tetra(4-carboxyphenyl)porphyrin with multi-component [Pr2Na3(NO3)(H2O)3] connectors

Goutam Nandi; Israel Goldberg

doi:10.1039/c4cc05601a

Fixation of CO₂ in bi-layered coordination networks of zinc tetra(4-carboxyphenyl)porphyrin with multi-component [Pr₂Na₃(NO₃)(H₂O)₃] connectors

Goutam Nandi^*, Israel Goldberg

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

CO₂ is fixed in a rare μ₂-η2 O, O bridging mode by bi-layered coordination networks of ZnTCPP tessellated along the four equatorial directions by [Pr₂Na₃(NO₃)(H₂O)₃]⁸⁺ connecting clusters in a 2 : 1 ratio (1), but not in the isomorphous free-base porphyrin analogue [(TCPPH₂)₂(Pr₂Na₃(NO₃)(H₂O)₃)]_n (2), revealing the crucial role of the zinc metal in this process.

Original language	English
Pages (from-to)	13612-13615
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	88
DOIs	https://doi.org/10.1039/c4cc05601a
State	Published - 9 Oct 2014

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abstract = "CO2 is fixed in a rare μ2-η2 O, O bridging mode by bi-layered coordination networks of ZnTCPP tessellated along the four equatorial directions by [Pr2Na3(NO3)(H2O)3]8+ connecting clusters in a 2 : 1 ratio (1), but not in the isomorphous free-base porphyrin analogue [(TCPPH2)2(Pr2Na3(NO3)(H2O)3)]n (2), revealing the crucial role of the zinc metal in this process.",

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AU - Goldberg, Israel

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N2 - CO2 is fixed in a rare μ2-η2 O, O bridging mode by bi-layered coordination networks of ZnTCPP tessellated along the four equatorial directions by [Pr2Na3(NO3)(H2O)3]8+ connecting clusters in a 2 : 1 ratio (1), but not in the isomorphous free-base porphyrin analogue [(TCPPH2)2(Pr2Na3(NO3)(H2O)3)]n (2), revealing the crucial role of the zinc metal in this process.

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Fixation of CO₂ in bi-layered coordination networks of zinc tetra(4-carboxyphenyl)porphyrin with multi-component [Pr₂Na₃(NO₃)(H₂O)₃] connectors

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