TY - JOUR
T1 - Field-Assisted Sensitivity Amplification in a Noble Metal Nanoparticle Decorated WO3/GO Hybrid FET-Based Multisensory Array for Selective Detection of Breath Acetone
AU - Bhardwaj, Radha
AU - Thakur, Uttam Narendra
AU - Ajmera, Pawan
AU - Singhal, Rahul
AU - Rosenwaks, Yossi
AU - Hazra, Arnab
N1 - Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2022/2
Y1 - 2022/2
N2 - Selective detection of acetone levels in exhaled human breath is important to diagnose complications of diabetes mellitus by the non-invasive route. In the current study, we are reporting a hybrid graphene oxide (GO) field-effect transistor (FET) based multisensory array for the selective detection of breath acetone by using a feature extraction and pattern recognition route. Backgated GO-FET was functionalized with WO3 flower-shaped nanostructures and noble metal (Au, Pd, Pt) nanoparticles to form hybrid FET sensors. By applying optimized gate voltages, the sensor response was enhanced several orders at room temperature. Therefore, an array of six sensors was tested in synthetic breath consisting of a complex mixture of multiple volatile organic compounds, various gases, 70% relative humidity and different levels of acetone. The sensors′ outcomes were then processed with phase space entire feature extraction method, and the different levels of acetone were differentiated in the synthetic breath by using Fisher discriminant analysis.
AB - Selective detection of acetone levels in exhaled human breath is important to diagnose complications of diabetes mellitus by the non-invasive route. In the current study, we are reporting a hybrid graphene oxide (GO) field-effect transistor (FET) based multisensory array for the selective detection of breath acetone by using a feature extraction and pattern recognition route. Backgated GO-FET was functionalized with WO3 flower-shaped nanostructures and noble metal (Au, Pd, Pt) nanoparticles to form hybrid FET sensors. By applying optimized gate voltages, the sensor response was enhanced several orders at room temperature. Therefore, an array of six sensors was tested in synthetic breath consisting of a complex mixture of multiple volatile organic compounds, various gases, 70% relative humidity and different levels of acetone. The sensors′ outcomes were then processed with phase space entire feature extraction method, and the different levels of acetone were differentiated in the synthetic breath by using Fisher discriminant analysis.
KW - FET sensors
KW - breath acetone detection
KW - feature extractions
KW - hybrid graphene oxide
KW - sensitivity amplification
UR - http://www.scopus.com/inward/record.url?scp=85122948978&partnerID=8YFLogxK
U2 - 10.1002/cnma.202100448
DO - 10.1002/cnma.202100448
M3 - מאמר
AN - SCOPUS:85122948978
VL - 8
JO - ChemNanoMat
JF - ChemNanoMat
SN - 2199-692X
IS - 2
M1 - e202100448
ER -