Femtosecond studies of acid-base reactions

B. Cohen; D. Huppert

Femtosecond studies of acid-base reactions

B. Cohen^*, D. Huppert

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

We have measured the direct proton transfer rate between a photo-acid, 8-hydroxypyrene 1,3,6 - trisulfonate (HPTS) and a base, acetate anion in water using a pump probe technique with ∼ 150 fs time. Our data analysis of aqueous solutions of 0.5M-4M sodium-acetate shows a good agreement with the diffusive model. The intrinsic rate constant at contact of the reactive species was found to be 1.6 · 10¹¹ M^-1s^-1.

Original language	English
Pages (from-to)	191-198
Number of pages	8
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics
Volume	24
Issue number	3
State	Published - 2000
Event	First Bi-National German-Israeli Workshop on Ultrafast Optical Technologies - Tel Aviv, Israel Duration: 12 Oct 1999 → 13 Oct 1999

Cite this

@article{625b96f6b4144fb5bb5e80c9c3870a08,

title = "Femtosecond studies of acid-base reactions",

abstract = "We have measured the direct proton transfer rate between a photo-acid, 8-hydroxypyrene 1,3,6 - trisulfonate (HPTS) and a base, acetate anion in water using a pump probe technique with ∼ 150 fs time. Our data analysis of aqueous solutions of 0.5M-4M sodium-acetate shows a good agreement with the diffusive model. The intrinsic rate constant at contact of the reactive species was found to be 1.6 · 1011 M-1s-1.",

author = "B. Cohen and D. Huppert",

year = "2000",

language = "אנגלית",

volume = "24",

pages = "191--198",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics",

issn = "1058-7268",

publisher = "Old City Publishing",

number = "3",

note = "First Bi-National German-Israeli Workshop on Ultrafast Optical Technologies ; Conference date: 12-10-1999 Through 13-10-1999",

}

TY - JOUR

T1 - Femtosecond studies of acid-base reactions

AU - Cohen, B.

AU - Huppert, D.

PY - 2000

Y1 - 2000

N2 - We have measured the direct proton transfer rate between a photo-acid, 8-hydroxypyrene 1,3,6 - trisulfonate (HPTS) and a base, acetate anion in water using a pump probe technique with ∼ 150 fs time. Our data analysis of aqueous solutions of 0.5M-4M sodium-acetate shows a good agreement with the diffusive model. The intrinsic rate constant at contact of the reactive species was found to be 1.6 · 1011 M-1s-1.

AB - We have measured the direct proton transfer rate between a photo-acid, 8-hydroxypyrene 1,3,6 - trisulfonate (HPTS) and a base, acetate anion in water using a pump probe technique with ∼ 150 fs time. Our data analysis of aqueous solutions of 0.5M-4M sodium-acetate shows a good agreement with the diffusive model. The intrinsic rate constant at contact of the reactive species was found to be 1.6 · 1011 M-1s-1.

UR - http://www.scopus.com/inward/record.url?scp=0034454675&partnerID=8YFLogxK

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.conferencearticle???

AN - SCOPUS:0034454675

SN - 1058-7268

VL - 24

SP - 191

EP - 198

JO - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

JF - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

IS - 3

T2 - First Bi-National German-Israeli Workshop on Ultrafast Optical Technologies

Y2 - 12 October 1999 through 13 October 1999

ER -

Femtosecond studies of acid-base reactions

Abstract

Other files and links

Fingerprint

Cite this