TY - JOUR
T1 - Fast non-exponential intramolecular electron transfer reactions in pentanediol solutions
AU - Huppert, Dan
AU - Ittah, Varda
AU - Masad, Asnat
AU - Kosower, Edward M.
PY - 1988/9/16
Y1 - 1988/9/16
N2 - Activationless, solvent-controlled fast intramolecular electron transfer (ET) kinetics are reported for three N-arylaminonaphthalenesulfon-N,N-dimethylamides over a wide temperature range in three pentanediols. A stretched exponential decay (Williams-Watts) using the longitudinal relaxation time, τL, fits the results. The temperature dependence of the observed dynamics is interpreted.
AB - Activationless, solvent-controlled fast intramolecular electron transfer (ET) kinetics are reported for three N-arylaminonaphthalenesulfon-N,N-dimethylamides over a wide temperature range in three pentanediols. A stretched exponential decay (Williams-Watts) using the longitudinal relaxation time, τL, fits the results. The temperature dependence of the observed dynamics is interpreted.
UR - http://www.scopus.com/inward/record.url?scp=2542543878&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(88)80056-3
DO - 10.1016/0009-2614(88)80056-3
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AN - SCOPUS:2542543878
SN - 0009-2614
VL - 150
SP - 349
EP - 356
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3-4
ER -